Safety Data Sheet for Carbon disulfide 102211. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. IF ON SKIN: Wash with plenty of soap and water. HANDLE WITH EXTREME CAUTION. additional knowledge and experience are gained. Take off Used in the manufacture of rayon and cellophane, in the manufacture of flotation agents and as a solvent. The permeation characteristics of mixtures can deviate considerably Prudent Practices in the Laboratory-the book that has served for decades as the standard for chemical laboratory safety practice-now features updates and new topics. Normalized breakthrough times CS2 plays a vital role in many of today's industrial processes. In the production of viscous rayon, heavy occupational exposures may occur during the opening of spinning machines and while cutting and drying. Found inside – Page 55It is not a fire hazard , but it liberates considerable heat when mixed with ... All are fire hazards , carbon disulfide being the most dangerous of the ... 0000020181 00000 n Avoid air, rust, halogens, metal azides, metals, oxidants; when exposed to heat or flame reacts violently with aluminum, chlorine, azides, hypochlorite, ethylamine diamine, ethylene imine, fluorine, metallic azides of lithium, potassium, cesium, rubidium and sodium, nitrogen oxides, potassium, zinc and (sulfuric acid plus permanganate). (Merck Index) At room temperature and atmospheric pressure CO 2 is a colourless and odourless gas and, because of … Found insideA flash point test does not flirnish conclusive information relating to the fire hazard of carbon disulfide-carbon tetrachloride base mixtures because the ... are damaged, end user should discontinue use 0000012975 00000 n The impure carbon disulfide that is usually used in most industrial processes is a yellowish liquid with an unpleasant odor, like that of rotting radishes. 0 Flammable over a wide vapor/air concentration range(1%-50%). 0000011843 00000 n This volume updates and combines two National Academy Press bestsellers--Prudent Practices for Handling Hazardous Chemicals in Laboratories and Prudent Practices for Disposal of Chemicals from Laboratories--which have served for more than a ... Chronic toxicity of carbon disulfide includes marked psychic disturbances ranging from extreme irritability to mania with hallucinations, tremors, auditory and visual disturbances, weight loss, blood dyscrasias. CARBON DISULFIDE†. NOTE: NO FURTHER DISCOUNT FOR THIS PRINT PRODUCT- OVERSTOCK SALE -Significantly reduced listprice The official Emergency Response Guidebook (ERG) is a guide for use by transporters, firefighters, police, and other emergency services ... When it comes to Carbon Disulfide Potential Hazards Right-To-Understand (Know) Placards and Signs you can count on Grainger. This volume explores the emerging field of neurobehavioral toxicology and the potential of behavior studies as a noninvasive and economical means for risk assessment and monitoring. Vapor ignites in contact with aluminum powder or fluorine. A different temperature may have significant influence on the Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. CalEnviroScreen. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. endstream endobj 31 0 obj <. 0000009636 00000 n If the vapor concentration exceeds 2 percent by volume or is unknown, self-contained breathing mask with full face should be used by all persons entering contaminated area. Review of Submarine Escape Action Levels for Selected Chemicals presents the subcommittee's findings after evaluation human data from experimental, occupational, and epidemiologic studies; data from accident reports; and experimental-animal ... The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. All liquid chemicals have been tested between approximately 20°C and Hazards identification Response :Get medical attention if you feel unwell. Carbon disulfide has been used in a variety of industrial applications for well over 100 years. Through its Hazard Communication Standard, the Occupational Safety and Health Administration (OSHA) requires employers inform workers about the hazards of chemicals they come in contact with through Safety Data Sheets (SDS) and appropriate labels. Chronic Health Hazard Assessments for Noncarcinogenic Effects _I.A. This is the first book to be published that is dedicated to the role of such nitrosocompounds in physiology, with particular emphasis on the nitrosocompounds that are endogenously formed in higher organisms and humans. Class IB Flammable Liquid: Fl.P. are outside our control, we make no warranties, express or implied, Reacts violently with azides, ethylamine ethylenediamine, ethylene imine. Alcoholics and those suffering from neuropsychic trouble are at special risk. The essays in Dangerous Trade provide an unprecedented broad perspective of the dangers stirred up by industrial activity across the globe, as well as the voices rasied to remedy them. %PDF-1.6 %���� 0000016824 00000 n Substance information for UN 1131 - Carbon disulfide based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials. The book provides an insight into this active and exciting field of research. determine the level of toxicity and the proper personal protective It is an important raw material for preparing viscose rayon and cellophane film. Anyone intending to use this information should first verify under or a recommendation to infringe any patent or technical information relative humidity per military standard MIL-STD-282. stated. 0000001698 00000 n Chemical Status; Reproductive Toxicity: Currently listed. It is subject to revision as The NIOSH Pocket Guide to Chemical Hazards presents information taken from the NIOSH/OSHA Occupational Health Guidelines for Chemical Hazards, from National Institute for Occupational Safety and Health (NIOSH) criteria documents and Current ... Target organs: Liver, Kidneys, eyes, heart, Central nervous system. equipment needed. 0000019351 00000 n It may be absorbed through the skin as a vapor or liquid, inhaled or ingested. Carbon disulfide 75-15-0 Hazard Summary Exposure to carbon disulfide occurs mainly in the workplace. Found inside – Page 81Carbon disulfide has been identified as an occupational reproductive hazard by NIOSH ( 244 ) . Accurate biological indicators of most solvent exposures ... evaluation under their specific end-use conditions, at their own discretion Found inside – Page 122Effects commonly caused by repeated exposure to carbon disulfide vapor are exemplified by a group of workers with a timeweighted average ( TWA ) exposure of ... Mixtures with lithium, sodium, potassium or dinitrogen tetraoxide may detonate when shocked. However, CO 2 is naturally present in the air we breathe at a concentration of about 0.037% and is not harmful to health at low concentrations. DANGER! Hidden health dangers lurk in many of the seemingly innocent products we encounter every day - a tube of glue in a kitchen drawer, a bottle of bleach in the laundry room, a rayon scarf on a closet shelf, a brass knob on the front door, a ... When heated to decomposition, emits highly toxic fumes of sulfur oxides and can react vigorously with oxidizing materials. 0000004534 00000 n HMIS (0 to 4) coronary heart disease. Material Safety Data Sheet Carbon Disulfide, P.A., Low in Benzene Content ACC# 00394 Section 1 - Chemical Product and Company Identification: MSDS Name: Carbon Disulfide, P.A., Low in Benzene Content Catalog Numbers: AC177280000, AC177285000 including, without limitation, no warranties of merchantability or fitness C 2 S may undergo hydrolysis catalyzed by nanosized titania and zirconia to form CO 2 and H 2 S. Material Safety Data Sheet or SDS for Carbon disulfide 102214 from Merck for download or viewing in the browser. 30 0 obj <> endobj Carbon disulfide is a colorless or faintly yellow liquid at room temperature and has an odor resembling chloroform or ether. It is volatile and flammable, and is used as a solvent, an insecticide, a building-block in organic chemistry, and in the manufacture of viscose rayon, cellophane, and bamboo fiber. Carbon disulfide 75-15-0 99 4. 5.2. Found inside – Page 108CARBON. DISULFIDE. CS2. EXTREMELY FLAMMABLE, GIVES OFF VERY POISONOUS VAPOR Physical Properties Colorless to yellow liquid with unpleasant odor; bp, ... 0000009227 00000 n Very highly flammable, very low flash point. Found inside – Page 144A hot gauze falling from a tripod into a laboratory sink containing some carbon disulfide initiated two explosions [2]. It is a very hazardous solvent ... 0000009870 00000 n Having a high vapour pressure and a low flash point means that CS 2 readily evaporates and can form explosive mixtures with air. Gives off irritating or toxic fumes (or gases) in a fire. Chem., 1956, 80, p.664]. CAUTION: This information is based upon technical data that Carbon disulfide is a highly volatile, flammable liquid with low ignition temperature. You will be subject to the destination website's privacy policy when you follow the link. Clear, colorless to pale yellow liquid, Strong, disagreeable odor. 0000004305 00000 n Found inside – Page 98Artists and Jewelers boron and boric acid cadmium and lead carbon disulfide Electrical workers boron and boric acid lead or cadmium compounds PCB's and ... Flammable liquid and severe inhalation hazard. 27°C unless otherwise stated. This book discusses six competency based learning objectives for all medical school students, discusses the relevance of environmental health to specific courses and clerkships, and demonstrates how to integrate environmental health into ... of DuPont or others covering any material or its use. 0000019586 00000 n The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent. Found insideThe volume's contributors demonstrate that implementation of a range of prevention strategies-presented in an essential package of interventions and policies-could achieve a convergence in death and disability rates that would avert more ... 0000005740 00000 n 0000005856 00000 n Carbon Disulfide Section 2. Skin: Wear appropriate personal protective clothing to prevent skin contact. startxref If fabric Safety Data Sheet for Carbon disulfide 102214. This book provides concise and clear explanation and look-up data on properties, exposure limits, flashpoints, monitoring techniques, personal protection and a host of other parameters and requirements relating to compliance with designated ... 0000001518 00000 n Vapors are readily ignited; the heat of a common light bulb may suffice. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. It was used as a grain fumigant. Found inside – Page 226CARBON - DISULFIDE - continued CARBON - MONOXIDE 77-157C NIOSH Manual of ... ( 1 set ) Hazard Evaluation and Technical Assistance Reports 72-021-040 HHE ... Office of Response and Restoration, About 10- 30% of carbon disulfide that the body absorbs leaves through the lungs; less than 1% leaves in the urine. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur USA.gov. May ignite or even explode when heated. Carbon disulfide spectrophotometric grade, ≥99%; CAS Number: 75-15-0; EC Number: 200-843-6; find Sigma-Aldrich-154709 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich Reference Dose for Chronic Oral Exposure (RfD) Substance Name - Carbon disulfide CASRN--75-15-0 Last Revised - 09/01/1990 The oral Reference Dose (RfD) is based on the assumption that thresholds exist for certain toxic effects such as cellular necrosis. National Oceanic and Atmospheric Administration. [Note: Reagent grades are foul smelling.]. Deeply researched and boldly presented, this book brings to light an industrial hazard whose egregious history ranks with those of asbestos, lead, and mercury. Clinical Neurotoxicology offers accurate, relevant, and comprehensive coverage of a field that has grown tremendously in the last 20 years. 63 0 obj <>stream Select Language. 0000002363 00000 n Colorless to faint-yellow liquid with a sweet ether-like odor. Explosion hazard : EXTREMELY FLAMMABLE GAS. Serged and bound seams are degraded by some hazardous liquid hazardous gas is not hydrogen, acetylene or carbon disulfide but is still applicable to a large range of installations. breakthrough time; permeation rates typically increase with dense, highly refractive, volatile, flammable and toxic liquid. DuPont believes to be reliable. <<4D2C49F4C7F6CC4B8CF8D42C44F88CA1>]>> 0000019985 00000 n Extremely flammable, vapour may catch flash fire. Carbon disulfide Revision Date 25-Apr-2019 Hazard Statements Highly flammable liquid and vapor Causes skin irritation Causes serious eye irritation Harmful if inhaled May cause drowsiness or dizziness Suspected of damaging fertility. Since conditions of use However, despite their universality, this is the first comprehensive resource that addresses their application to fire debris analysis. of garment to avoid potential exposure to chemical. l��8_:��&Ј�?�K��Boσ����y +�\����� _p�b-�^����_��x�C\a�(���TS7nNm�W�9qē%:ߞ�G] �'�1 F�S~��7ԛ��a+=�����* 7s���C��!>倃e{?����t���#�l'ܛ`�^n{0?�ӌ���F��_+M�;W�jD��E����j�ƹ6�E�F���� c�m Carbon disulfide with formula CS2 is a colorless volatile liquid . The compound is commonly used in organic chemistry as a building block, as well as a non-polar industrial and chemical solvent. This has a "ether-like" odor but usually industrial samples are polluted with impurities that smell foul. Unless otherwise stated, permeation was measured for single chemicals. This two-volume compendium focuses on reactivity risks of chemicals, alone and in combination; toxicity hazards are only included for unexpected reactions giving volatile poisons Predict, avoid, and control reactivity danger with this ... Acute (short-term) inhalation exposure of humans to carbon disulfide has caused changes in breathing and chest pains. 0000001301 00000 n Visit BYJU'S to understand the properties, structure, and uses of Carbon Disulfide (CS2) explained by … Carbon disulfide, also spelled as carbon disulphide, is a neurotoxic colorless volatile liquid with the formula CS2. Found inside – Page iDeeply researched and boldly presented, this book brings to light an industrial hazard whose egregious history ranks with those of asbestos, lead, and mercury. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 below 73°F and BP at or above 100°F. First-aid measures General Advice Show this safety data sheet to the doctor in attendance. The information set forth herein reflects laboratory The technique Carbon Disulfide; Carbon Disulfide . Found inside – Page 197A hot gauze falling from a tripod into a laboratory sink containing some carbon disulfide initiated two explosions [2]. It is a very hazardous solvent ... National Ocean Service, It is the user's responsibility to 0000008102 00000 n Insoluble in water and more dense (10.5 lb / gal) than water. Safely storing hazardous materials is essential to any safety program and to prevent injuries, fires, and unhealthful conditions. Zr��>A����wh݋ Lowest lethal dose for humans has been reported at 14 mg/kg or 0.98 grams for a 70 kg person. Carbon disulfide evaporates at room temperature, and the from the permeation behavior of the individual chemicals. All chemicals have Widely acknowledged as the most comprehensive book on its subject, this book offers concise, practical guidance on the use of electrodiagnostic techniques for investigating problems of both the central and peripheral nervous systems. General hazards of Carbon Dioxide For over a century CO 2 has been recognised as a workplace hazard at high concentrations. The toxicological properties of this material have not been fully investigated. Safety Data Sheet for Carbon disulfide 102214. Forms … CARBON DISULFIDE International Programme on Chemical Safety Poisons Information Monograph 102 Chemical 1. 0000000016 00000 n Carbon disulfide easily forms explosive mixtures with air and catches fire very easily; it is dangerous xref 0000006990 00000 n More information about Carbon Disulfide. Found insideThis unique book provides the reader with a concise compilation of information regarding the use of environmental forensic techniques for age dating and identification of the source of a chlorinated solvent release. Carbon disulfide evaporates at room temperature, and the vapor is more than twice as heavy as air. 0000003611 00000 n (the time at which the permeation rate is equal to 0.1 µg/cm2/min) This volume updates and combines two National Academy Press bestsellers--Prudent Practices for Handling Hazardous Chemicals in Laboratories and Prudent Practices for Disposal of Chemicals from Laboratories--which have served for more than a ... Web site owner: Suitable extinguishing media : Carbon dioxide, Dry chemical, Water spray or fog. Hence sinks in water. The authors [48] found ECG patterns indicating coronary artery disease in 5.6% of the subjects exposed to carbon disulfide at average concentrations above 120 mg/ eu m (39 ppm), in 3.6% of those exposed at 60 mg/cu m (19 ppm), and in 1.2% of the controls. reported in minutes. National Oceanic and Atmospheric Administration. Skin: May cause skin irritation. Found insideWe are republishing these classic works in affordable, high quality, modern editions, using the original text and artwork. When pregnant animals received large doses of carbon disulfide in their diet, some of the newborns died or had birth defects.Skin contact with spilt carbon disulfide can lead … becomes torn, abraded or punctured, or if seams or closures fail, or if _l. f Contact can irritate and burn the skin and eyes. CARBON DISULFIDE has an extremely low autoignition temperature (125°C). The impure carbon disulfide that is usually used in most laboratory and industry processes is a colorless to faintly yellow liquid with a strong, disagreeable cabbage-like odour detectable at 0.016 to 0.42 ppm. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Sulphur oxides Flash back possible over considerable distance., Container explosion may occur under fire conditions., Vapours may form explosive mixture with air., May explode when heated. Product Name Carbon disulfide. 1.4.Physical properties-Pure carbon disulfide is a colorless liquid with a pleasant odour that is like the smell of chloroform. Decomposes on standing for a long time. this information. Sodium amide forms toxic and flammable H2S gas with CS2. Section 15. CDC twenty four seven. NAME 1.1 Substance Carbon disulfide 1.2 Group Inorganic carbon compound 1.3 Synonyms Carbon bisulfidey, Carbon sulfide, Dithiocarbonic anhydride, Dithiomethane, Schwefelkohlenstoff, solfuro di carbonio, sulfure de carbone, sulphocarbonic anhydride, 1.4 … f Carbon Disulfide may be a TERATOGEN and may cause reproductive damage.
You can also be exposed by skin contact with soil, water, or other substances that contain it. [Note: Vapors may be ignited by contact with ordinary light bulb. dizziness, headache, poor sleep, lassitude (weakness, exhaustion), anxiety, anorexia, weight loss; psychosis; polyneuropathy; Parkinson-like syndrome; ocular changes; coronary heart disease; gastritis; kidney, liver injury; eye, … Chemical Listing Details. Vapors are heavier than air. Immediate medical attention is required. including trade names and synonyms. Found inside – Page 81Carbon disulfide has been identified as an occupational reproductive hazard by NIOSH (244). Accurate biological indicators of most solvent exposures, ... Strong oxidizers; chemically-active metals such as sodium, potassium & zinc; azides; rust; halogens; amines Material Safety Data Sheet or SDS for Carbon disulfide 102214 from Merck for download or viewing in the browser. Found inside – Page 278OTHER HAZARDS Carbon disulfide is a highly flammable , volatile liquid with a low flash point ( -22 F ) , wide explosive range and an autoignition ... rates than the fabric. Health and Safety Executive Page 1 of 28 Assessment of the major hazard potential of carbon dioxide (CO 2) A paper by: Dr Peter Harper, Health and Safety Executive (HSE) Advisers: Ms Jill Wilday (HSL) and Mr Mike Bilio (OSD) Introduction Carbon dioxide (CO 2) is a substance which has many domestic and commercial When working with carbon disulfide there are three very important things to remember: It is extremely flammable. Emits highly toxic fumes of oxides of sulfur when heated to decomposition [Bretherick, 5th ed., 1995, p. 663]. Adequate solutions exist which are compatible with all gases and area classifications. temperature. India (RTO) RQ, UN1131, Carbon Disulfide, 3(6.1), PG 3. person. Flammable liquid, keep away from all ignition sources. Inst. May be fatal if swallowed or Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Ignition temperature dangerously low: 212F. (EPA, 1998), The material affects the central nervous system, cardiovascular system, eyes, kidneys, liver, and skin. Prolonged or repeated exposure can cause drying and cracking of the skin with redness and blisters. 0000019795 00000 n Found inside – Page 1INTRODUCTION The recognition of workplace hazards has been steadily ... carbon disulfide , at levels below the current United States Threshold Limit Value ... ], inhalation, skin absorption, ingestion, skin and/or eye contact, dizziness, headache, poor sleep, lassitude (weakness, exhaustion), anxiety, anorexia, weight loss; psychosis; polyneuropathy; Parkinson-like syndrome; ocular changes; coronary heart disease; gastritis; kidney, liver injury; eye, skin burns; dermatitis; reproductive effects, central nervous system, peripheral nervous system, cardiovascular system, eyes, kidneys, liver, skin, reproductive system, Centers for Disease Control and Prevention.

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